CSPI says it might reconsider its rating if specifications for food-grade titanium dioxide in the U.S. are updated to ensure nanoparticles are minimized, and new studies are conducted to assess its capacity to cause cancer or other health problems.
TIO2 Products Supplier A Comprehensive Guide to Titanium Dioxide③ Paper making industry: Paper making and paper products industry is the third largest application industry of titanium dioxide. Paper using titanium dioxide has good whiteness, high strength, luster, thin and smooth, and is not easy to penetrate when printing. Under the same conditions, the opacity is 10 times higher than that of paper using calcium carbonate and talc powder, and the weight can also be reduced by 15% to 30%. The amount of titanium dioxide in decorative paper accounts for 20%~40% of its raw materials, and the amount of titanium dioxide in other papers is about 1%~5%. Due to the continuous adjustment of the industrial structure of the paper products industry from 2016 to 2018, according to the data of China Paper Association, the output of China's paper products in 2019 was 72.19 million tons, a significant year-on-year increase of 29.4%, and the use of titanium dioxide increased significantly.
TiO2 comes in many different forms. However, only a few of these forms are considered food-grade (acceptable to be added to food). Many studies that raised concern about the safety of TiO2, including the concern for genotoxicity, used forms of TiO2 that are not considered acceptable for use in food and have different properties than food-grade TiO2. Other studies did use food-grade TiO2, but took steps to break the material down into smaller particles than what would normally be found in food.
Furthermore, titanium dioxide is finding increasing use in the cosmetics industry. It is commonly added to sunscreens for its ability to block both UVA and UVB radiation, offering broad-spectrum protection against harmful sunlight. Its antimicrobial properties are also advantageous in personal care products like deodorants and makeup, where it helps to extend shelf life and maintain product safety.Titanium dioxide is a mineral that’s used as a white coloring in a variety of products, including sunscreens, cosmetics, paints, and plastics. The pigment grade is also known as titanium white, pigment white 6, or CI 77891; it's the whitest and brightest of all known pigments.
In conclusion, understanding the dynamics of lithopone prices and its suppliers is crucial for businesses that rely on this pigment. As the industry evolves, suppliers need to adapt to changing market conditions, environmental regulations, and consumer preferences to maintain their competitive edge. Meanwhile, buyers must stay informed about these changes to make strategic purchasing decisions that balance cost-effectiveness with product quality.This precipitate is not suitable for a pigment until it is filtered, dried, crushed, heated to a high temperature and quenched in cold water. The second heating in a muffle furnace at 725 °C produces crystals of the right optical size.
Overwhelmingly, research that’s relevant to human eating patterns shows us that E171 is safe when ingested normally through foods and drugs (1,2).
The Asian market was favorable to the rising price trends of titanium dioxide in the first quarters of 2023. The prices inclined gradually with some slight fluctuations. The positive outlook of the market was a direct effect of removing covid restrictions, upscaling industrial production, and high speed of market recovery.
In addition to the toxic effects of TiO2 NPs, discussed in previous chapters, these NPs have been also shown to promote photosynthesis and nitrogen metabolism, resulting in the enhanced growth of spinach. It increases the absorption of light and accelerates the transfer and transformation of the light energy. It was also found that treatment with nano-sized TiO2 significantly increased the level of antioxidant enzymes, and decreased the ROS accumulation and malonyldialdehyde content in spinach chloroplasts under visible and UV irradiation. TiO2 NPs also increased the superoxide dismutase activity of germinating soybean, enhanced its antioxidant ability, and promoted seed germination and seedling growth.
Food containing titanium dioxide that is lawfully placed on the EU market before 7 August 2022 may remain on the market until its date of minimum durability or its ‘use-by’ date has passed. Food produced or placed on the market after 7 August 2022 cannot contain titanium dioxide. The ban on the use of titanium dioxide is effective in each EU Member State, and in Northern Ireland. Some third countries, such as the United Kingdom (excluding Northern Ireland), continue to permit the use of titanium dioxide.
Moreover, the use of talc and titanium dioxide in the manufacturing of rubber products is also highly beneficial. These minerals can improve the tear strength, abrasion resistance, and flexibility of rubber materials These minerals can improve the tear strength, abrasion resistance, and flexibility of rubber materials
With 30% of the world's lithopone factories located in China, the country has become a major player in the global lithopone market. Chinese manufacturers are able to produce lithopone at a competitive price, making it an attractive option for companies looking to reduce their production costs. In addition, China's large production capacity ensures a steady and reliable supply of lithopone to markets around the world.
Lithopone is added to plastic resin systems to enhance UV protection of the final plastic products that includes outdoor plastics and automotive plastics. It is used as a white pigment for plastics such as polyolefin, vinyl resin, ABS resin, polystyrene, polycarbonate, nylon, and polyoxymethylene (POM). It ensures that UV rays do not penetrate and damage the product and its appearance.
One of the key players in the titanium dioxide manufacturing industry is CAS 13463-67-7. This factory is known for its high-quality products and state-of-the-art facilities. With a focus on innovation and sustainability, CAS 13463-67-7 has become a go-to choice for companies looking to source titanium dioxide for their dyes and pigments.
French researchers studied how and where E171 nanoparticles enter the bloodstream, first studying the route through pigs and then in vitro with human buccal cells, for a 2023 study published in the journal Nanotoxicology. The research showed that the nanoparticles absorbed quickly through the mouth and then into the bloodstream, before damaging DNA and hindering cell regeneration.
Pure PVB is non-toxic and harmless to human body. In addition, ethyl acetate or alcohol can be used as solvent, so PVB is widely used in printing ink of food containers and plastic packaging in European and American countries.
Storage safety properties
PVB can be stored for two years without affecting its quality as long as it is not in direct contact with water; PVB shall be stored in a dry and cool place and avoid direct sunlight. Heavy pressure shall be avoided during PVB storage.
Solubility
PVB is soluble in alcohol, ketone, ester and other solvents. The solubility of various solvents changes according to the functional group composition of PVB itself. Generally speaking, alcohol solvents are soluble, but methanol is more insoluble for those with high acetal groups; The higher the acetal group, the easier it is to dissolve in ketone solvents and ester solvents;
PVB is easily soluble in cellosolve solvents; PVB is only partially dissolved in aromatic solvents such as xylene and toluene; PVB is insoluble in hydrocarbon solvents.
Viscosity characteristics of PVB solution
The viscosity of PVB solution is greatly affected by the formula of solvent and the type of solvent; Generally speaking, if alcohol is used as solvent, the higher the molecular weight of alcohol, the higher the viscosity of PVB solution;
Aromatic solvents such as xylene and toluene and hydrocarbon solvents can be used as diluents to reduce the viscosity of PVB solution; The effect of PVB chemical composition on viscosity is summarized as follows: under the same solvent and the same content of each base, the higher the degree of polymerization, the higher the solution viscosity; Under the same solvent and the same degree of polymerization, the higher the acetal group or acetate group, the lower the solution viscosity.
Dissolution method of PVB
Where mixed solvents are used, the dissolution step is to first put aromatic solvents (such as xylene, toluene, etc.) or ester solvents (such as n-butyl acetate, ethyl acetate, etc.) into the mixing, slowly put PVB into the mixing, and then add alcohol solvents (such as n-butanol, ethanol, etc.) after PVB is dispersed and expanded,
At this time, the dissolution time can be shortened by heating; Using this dissolution method, the formation of lumpy PVB can be avoided (because the dissolution time will be several times after the formation of lumpy PVB), so the dissolution speed can be accelerated. Generally, the ratio of aromatic and alcohol solvents is 60 / 40 ~ 40 / 60 (weight ratio), and PVB solution with low viscosity can be prepared.
The solvent composition contains 2 ~ 3wt% water, which can improve the hydrogen bonding strength of alcohol solvents and help the solubility of PVB.
Processing properties
Although PVB resin is a thermoplastic, it has little processability before plasticizer is added. Once plasticizer is added, its processability is very easy.
The purpose of general coatings and adhesives is to change the resin characteristics by adding plasticizers to meet the application requirements, such as film softness, reducing the TG point of the resin, reducing the heat sealing temperature, maintaining low-temperature softness, etc.
Compatibility
PVB can be compatible with a variety of resins, such as phenolic resin, epoxy resin, alkyd resin and MELAMINE resin.
B-08sy, b-06sy and b-05sy with high acetal degree can be mixed with nitrocellulose in any proportion. PVB and alkyd resin are partially compatible. General PVB is compatible with low molecular weight epoxy resin, while high molecular weight epoxy resin needs PVB with high acetal degree to be compatible with each other.
≤0.4
Titanium dioxide is used in the production of paper and textiles to improve whiteness, brightness, opacity and durability. It’s often used in fabrics, yarns, paper and other fibers.